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991.
Ao and Hanson, and Guiduli, Gyárfás, Thomassé and Weidl independently, proved the following result: For any tournament score sequence S = (s1, s2, … ,sn) with s1≤s2 ≤ … ≤ sn, there exists a tournament T on vertex set {1,2, …, n} such that the score of each vertex i is si and the sub‐tournaments of T on both the even and the odd indexed vertices are transitive in the given order; that is, i dominates j whenever i > j and i ≡ j (mod 2). In this note, we give a much shorter proof of the result. In the course of doing so, we show that the score sequence of a tournament satisfies a set of inequalities which are individually stronger than the well‐known set of inequalities of Landau, but collectively the two sets of inequalities are equivalent. © 2001 John Wiley & Sons, Inc. J Graph Theory 38: 244–254, 2001 相似文献
992.
Shan Li Zhi Qin Zhenghu Shen Xiaorong Tan Ping Shi Yafu Wang Ruolan Dai 《Journal of Radioanalytical and Nuclear Chemistry》2001,247(3):545-548
A convenient procedure for preparing a multitracer solution from irradiated silver foils by 80 MeV/nucleon 20Ne ions was developed. The carrier-free and salt-free solution containing 19 essential elements or trace elements for plant growth were prepared, and had been applied to study the regulation effect of metal ions on somatic embryogenesis of Lycium barbarum L. 相似文献
993.
The total capability of an atom attracting valence electrons can be measured by the sum of ionization energies of valence electron in a ground‐state free atom plus its electron affinity called Total Attracting Energy, TAE = ΣniEi + EA, where, Ei is the ionization energy of the ith valence‐shell electron in a ground‐state free atom, ni is the number of valence‐shell electron bearing energy Ei, and EA is the electron affinity. And the electronegativity χCL is proportional to the average of TAE, AAE = TAEav, divided by Σni, the number of atomic valence‐shell electrons. χCL = 0.1813 TAEav = 0.1813 AAE = 0.1813 TAE/Σni, = 0.1813 (ΣniEI + EA)/Σni. Further, the atomic valence orbital electronegativity can be also obtained from the TAE value of an atom. Some discussions were made on several special aspects such as scale of rare gases, comparisons with Pauling's and Allen's scales, etc. 相似文献
994.
A new method of indirect determination of ascorbic acid with ammonium sulfate and ethanol by extraction and flotation of copper in the presence of thiocyanate has been studied in this paper. The study shows that a small amount of Cu(II) is reduced to Cu(I) by ascorbic acid, then Cu(I) precipitates with SCN?. In the course of phase separation of ethanol from water, the precipitated CuSCN is extracted and stays in the interface of ethanol and water. A good linear relationship is observed between the extraction yield of Cu(II) and the amount of ascorbic acid. The detection limit for ascorbic acid is 1 10?5 M. Every parameter has been optimized and the reaction mechanism has been studied. The method is simple, rapid (5 min) and suffers from few interferences of common anions and cations. It has been successfully applied for the determination of ascorbic acid in pharmaceuticals and fruits. 相似文献
995.
The far infrared spectrum from 370 to 50 cm−1 of gaseous 2-bromoethanol, BrCH2CH2OH, was recorded at a resolution of 0.10 cm−1. The fundamental O–H torsion of the more stable gauche (Gg′) conformer, where the capital G refers to internal rotation around the C–C bond and the lower case g to the internal rotation around the C–O bond, was observed as a series of Q-branch transitions beginning at 340 cm−1. The corresponding O–H torsional modes were observed for two of the other high energy conformers, Tg (285 cm−1) and Tt (234 cm−1). The heavy atom asymmetric torsion (rotation around C–C bond) for the Gg′ conformer has been observed at 140 cm−1. Variable temperature (−63 to −100°C) studies of the infrared spectra (4000–400 cm−1) of the sample dissolved in liquid xenon have been recorded. From these data the enthalpy differences have been determined to be 411±40 cm−1 (4.92±0.48 kJ/mol) for the Gg′/Tt and 315±40 cm−1 (3.76±0.48 kJ/mol) for the Gg′/Tg, with the Gg′ conformer the most stable form. Additionally, the infrared spectrum of the gas, and Raman spectrum of the liquid phase are reported. The structural parameters, conformational stabilities, barriers to internal rotation and fundamental frequencies have been obtained from ab initio calculations utilizing different basis sets at the restricted Hartree–Fock or with full electron correlation by the perturbation method to second order. The theoretical results are compared to the experimental results when appropriate. Combining the ab initio calculations with the microwave rotational constants, r0 adjusted parameters have been obtained for the three 2-haloethanols (F, Cl and Br) for the Gg′ conformers. 相似文献
996.
Guang‐Min Shen Chien‐Chih Chen Raymond Chien‐Chao Tsiang 《Journal of polymer science. Part A, Polymer chemistry》2001,39(15):2625-2632
An amphiphilic styrenic block copolymer, polystyrene‐block‐polybutadiene‐block‐poly[oxymethylene‐alt‐oligo(oxyethylene)] (PS‐b‐PB‐b‐POME), was synthesized through a polycondensation reaction of low molecular weight poly(ethylene glycol) and dichloromethane in the presence of hydroxypropylated polystyrene‐block‐polybutadiene (PS‐b‐PB‐OH) used as a monofunctional chain‐capping reagent. PS‐b‐PB‐OH was in turn prepared via an anionic synthesis of PS‐b‐PB followed by oxetane capping and methanol quenching. Although PS‐b‐PB‐OH has insignificant hydrophilicity, PS‐b‐PB‐b‐POME containing both the hydrophobic PS‐b‐PB segment and the hydrophilic POME segment had an improved emulsifying capability and effectively decreased the interfacial tension between water and toluene. The hydrophile–lipophile balance value of this amphiphilic PS‐b‐PB‐b‐POME copolymer, consisting of 86 wt % of the POME segment and 14 wt % of the PS‐b‐PB segment, was 17.2. The molecular weight of the copolymer molecule was determined by gel permeation chromatography–multi‐angle laser light scattering, and the microstructure was analyzed using 1H NMR. © 2001 John Wiley & Sons, Inc. J Polym Sci Part A: Polym Chem 39: 2625–2632, 2001 相似文献
997.
人工神经网络法预测炸药组分的色谱保留值参数 总被引:1,自引:0,他引:1
以分子拓扑指数作为炸药组分的结构描述符 ,利用反向传播算法 (BP)人工神经网络 ,以Sigmoid函数为传递函数 ,分子连接性指数0 χ ,1χ ,2 χ与边邻接指数 (ε)为输入向量 ,反相高效液相色谱保留值参数logkw 和S为输出向量 ,将输入向量归一化至 - 3~ 3区间 ,输出向量归一化至 0~ 1区间 ,网络精度取 0 5 ,学习步长 η的初始值取0 2 ,动量因子α取 0 5 ,通过对 2 0种炸药的网络模型进行训练 ,建立了炸药分子结构与logkw 和S之间的定量模型。结果表明 ,该模型较好地反映了炸药分子结构与保留值之间的关系。 相似文献
998.
A novel soluble ladderlike polysilsesquioxane containing reactive ester groups (Ester-T) was synthesized for thefirst time by stepwise coupling polymerization including preammonolysis, controlled hydrolysis and polycondensation. Themonomer, 3-trichlorosilylpropoxy 4-acetoxybenzoate (M), was synthesized by hydrosilylation of allyloxy 4-acetoxybenzoatewith trichlorosilane in the presence of dicyclopentadienylplatinum (II) chloride (Cp_2PtCl_2) catalyst. Combination of FTIR,~1H-NMr, ~(13)C-NMR, ~(29)Si-NMR, XRD, DSC, TGA and VPO methods was used to demonstrate that the polymer obtained hasan ordered ladderlike structure. The synthesized Ester-T may have promising applications as a precursor of advanced functional polymers. 相似文献
999.
Jing-ying Zhang Shi-dong Kan Yu-guang Ma Jia-cong Shen Key Lab for Supramolecular Structure Spectroscopy of Ministry of Education Jilin University Changchun China 《高分子科学》2001,(6):591-596
The electroluminescence (EL) produced by a highly luminescent phosphorescent dye Cu_4(C≡CPh)_4L_2 (L = 1.8-bis(di-phenylphosphino)-3, 6-dioxaoctane, Cu_4) doped polymer as emitting layer is reported. The effects o f the chargeinjection balance on the polymers, in particular, poly(N-vinylcarbazole) (PVK) have been studied by usingphotoluminescence and elecholuminescence spectroscopy. Changes in the emission spectra demonstrate the influence of thecharge injection balance on the formation ratio of triplet and singlet excitons. (This provides a new technical approach torealize the color patterning in polymer LEDs. 相似文献
1000.
罗丹明B—I3^—离子缔合物共振散射测定环境水样中的铬(Ⅵ)和铬(Ⅲ) 总被引:4,自引:0,他引:4
研究在磷酸介质中,罗丹明B与I3^-的离子缔合物的共振散射光谱。确定了散射光强度与溶液中Cr(VI)浓度的关系。提出了共振散射测定Cr(VI)的新方法,方法的检出限为2.2ug/L,线性范围为10.0-500ug/L,结合离子交换分离法,用于环境水样中铬的形态分析,结果满意。 相似文献